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Oooh... Idea... Maybe your pre-Cap guy was there when the post-Cap soldiers were being trained, and he discovered HYDRA had infiltrated the lab and was planning to use the super soldiers as sleeper agents to help Nazi Germany win the war, so he is the one who blew up the lab and has been secretly fighting HYDRA all these years. Then we could even have HYDRA partially responsible for the mutant outbreak .
And another thing, for my character, could it be possible for him to have a bit of personal crisis when his symbiote spawns for the first time? Like the heightened adrenaline surges and sensations from the suit affecting him like a pregnant woman's rapidly shifting emotions and temper, thus making him a bit unstable so he tries to close off others for their own good. And then his symbiote gives its first spawn and from there it could go either Winter Soldier, Spiderman, Deadpool or Captain Jack Sparrow on the world. Hehe would be amusing if I accidentally made a new Deadpool whose origin is as a symbiote, or got the real version of Deadpool attached to a symbiote, man that would be chaos.
One option you could say is that he has completely control over his skin cells, and thus can change its color and the shape of his face. Maybe his healing factor was not automatic, and he had to learn to will his skin cells to repair torn flesh faster than normal. In doing that, he discovered how to will his skin to do much more, including altering appearance. But maybe moving his cells at higher than average rate boosts his metabolism, and he has to consume more food to maintain his energy or something. Just an idea .